PUBLICATIONS

2021

(82)   Quantification of Ni-N-O Bond Angles and NO Activation by X-ray Emission Spectroscopy 

Phu, P. N.; Gutierrez, C. E.; Kundu, S.; Sokaras, D.; Kroll, T.; Warren, T. H.*, Stieber, S. C. E.* 
Inorg. Chem. 202160, 736-744.

2020

(81)   A Three Coordinate Copper(II) Alkynyl Complex in C−C Bond Formation: The Sesquicentennial of the Glaser Coupling 

Bakhoda, A.;  Okoromoba, O.; Greene, C.; Borougeni, M. R.; Bertke, J. A.; Warren, T.H.* 
J. Am. Chem. Soc. 2020142, 18483-18490.

(80)   Decomposition of Vanadium(V) Alkylidenes Relevant to Olefin Metathesis 

Farrell, W.S.*, Greene, C.; Ghosh, P.; Warren, T. H.; Zavalij, P. Y. 
Organometallics 202039, 3906-3917.

(79)   Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation

Bakhoda, A.;  Wiese, S.; Greene, C.; Figula, B. C.; Bertke, J. A.; Warren, T.H.* 
Organometalics 202039, 1710-1718.

(78)   Decarboxylative C(sp(3))-S Coupling via Cu-Photoredox Catalysis

Bakhoda, A.; Warren, T. H. Chem 20206, 1048-1050. Chem Preview synopsis

(77)   Lewis Acid Coordination Redirects S-Nitrosothiol Signaling Output

Hosseininasab, V.; McQuilken, A. C.; Bakhoda, A.; Bertke, J. A.; Timerghazin, Q. K.*; Warren, T. H.* 
Angew. Chem. Int. Ed. 202059, 10854-10858. Noted as a Very Important Paper

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2019

(76)   Tris(pyrazolyl)borate Copper Hydroxide Complexes Featuring Tunable Intramolecular H-bonding

Gardner, E. J.; Cobb, C. R.; Bertke, J. A.; Warren, T. H.* 
Inorg. Chem. 201958, 11248-11255.

(75)   Copper-Catalyzed C(sp3)-H Amidation: Sterically Driven Primary and Secondary C-H Site-Selectivity

Bakhoda, A.; Jiang, Q.; Bertke, J. A.; Cundari, T. R.*; Warren, T. H.* 
Angew. Chem. Int. Ed201958, 3421-3425.

 

 

 

 

 

 

(74)   Nitrosyl Linkage Isomers: NO Coupling to N2O at a Mononuclear Site 

Kundu, S.; Phu, P. N.; Ghosh, P.; Kozimor, S. A.; Bertke, J. A.; Stieber, S. C. E.*; Warren, T. H.*
J. Am. Chem. Soc. 2019, 141, 1415-1419. 

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2017

(73)   Three-Coordinate Copper(II) Aryls: Key Intermediates in C–O Bond Formation

Kundu, S.; Greene, C.; Williams, K. D.; Salvador, T. K.; Bertke, J. A.; Cundari, T. R.*; Warren, T. H.* 
J. Am. Chem. Soc.2017139, 9112-9115.

 

(72) Elusive Terminal Copper Arylnitrene Intermediates

Bakhoda, A.; Jiang, Q.; Bertke, J. A.; Cundari, T. R.*; Warren, T. H.* 
Angew. Chem. Int. Ed.201756, 6426-6430.

 

(71)   Copper(II) Activation of Nitrite: Nitrosation of Nucleophiles and Generation of NO by Thiols

Kundu, S.*; Kim, W. Y.; Bertke, J. A.; Warren, T. H.*
J. Am. Chem. Soc., 2017139, 1045-1048.
(JACS Article Spotlight)

 

(70)   Nitric oxide release via oxygen atom transfer from nitrite at copper(II)

Sakhaei, Z.; Kundu, S.; Donnelly, J. M.; Bertke, J. A.; Kim, W. Y.; Warren, T. H.* 
Chem. Commun., 201753, 549-552.

(69)   The Chemistry of a Non-Interacting Vicinal Frustrated Phosphane/Borane Lewis Pair

Elmer, L-M.; Kehr, G.; Daniliuc, C. G.; Siedow, M.; Eckert, H.; Tesch, M.; Studer, A.; Williams, K.; Warren, T. H.; Erker, G.* Chem. Eur. J.2017, 23, 6056-6068.

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2016

(68)   Copper Catalyzed sp3 C-H Etherification with Acyl Protected Phenols

Salvador, T. K.; Arnett, C. H.; Kundu, S.; Sapiezynski, N. G.; Bertke, J. A..; Boroujeni, M. R.; Warren, T. H.* 
J. Am. Chem. Soc.2016138, 16580-16583.

 

 

 

 

 

 

(67)   A Frustrated and Confused Lewis Pair

McQuilken, A. C.; Dao, Q. M.; Cardenas, A. J. P.; Bertke, J. A.; Grimme, S.*; Warren, T. H.*
Angew. Chem. Int. Ed.201655, 14335-14339.

 

 

 

 

 

(66)  Redox Noninnocence of Nitrosobenzene at Nickel

Kundu, S.*; Stieber, S. C. E.*; Ferrier, M. G.; Kozimor, S. A.; Bertke, J. A.; Warren, T. H.*
Angew. Chem. Int. Ed.201655, 10321-10325.

 

 

 

(65)   A Dinitrogen Dicopper(I) Complex via a Mixed-Valence Dicopper Hydride 

Zhang, S.; Fallah, H.; Gardner, E. J.; Kundu, S.; Bertke, J. A.; Cundari, T. R.*; Warren, T. H.* 
Angew. Chem. Int. Ed.201655, 9927-9931.
(Hot Paper)

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(64)   An Ethylene-Bridged Phosphane/Borane Frustrated Lewis Pair Featuring the -B(Fxyl)2Lewis Acid Component

Wang, L.; Samigullin, K.; Wagner, M.; McQuilken, A. C.; Warren, T. H.; Daniliuc, C. G.; Kehr, G.; Erker, G.*
Chem. Eur. J.201622, 11015-11021.

(63)   A Motif for Reversible Nitric Oxide Interactions in Metalloenzymes

Zhang, S.; Melzer M. M.; Nermin Sen, S.; Çelebi-Ölçüm, N.*; Warren, T. H.* 
Nat. Chem.20168, 663-669. 

 

(62)  FLPNO Nitroxide Radical Formation by a 1,1-Carboboration Route

Liedtke, R.; Eller, C.; Daniliuc, C. G.; Williams, K.; Warren, T. H.: Tesche, M.; Studer, A.; Kehr, G.; Erker, G* Organometallics201635, 55-61.

 

(61)  Frustrated Lewis Pair Chemistry Derived from Bulky Allenyl and Propargyl Phosphanes

Rosorius, C.; Möricke, J.; Wibbeling, B.; McQuilken, A. C.; Warren, T. H.; Daniliuc, C. G.; Kehr, G.; Erker, G.* 
Chem. Eur. J.201622,1103-1113.

 

(60)  Cooperative 1,1-addition reactions of vicinal phosphane/borane frustrated Lewis pairs

Cardenas, A. J. P.; Hasegawa, Y.; Kehr, G.; Warren, T. H.*; Erker, G.* 
Coord. Chem. Rev. 2016306, 468-482.

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2015

(59)  Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal-ligand interactions. 
Tomson, N. C.*; Williams, K. D.; Dai, X.; Sproules, S.; DeBeer, S.; Warren, T. H.*; Wieghardt, K.* 
Chem. Sci. 20156, 2474-2487.

(58)  P/B Ketene Adduct Formation from Acyl Chlorides at a Vicinal Phosphane/Borane Frustrated Lewis Pair. Frömel, S.; Radermacher, G.; Wibbeling, B.; Daniliuc, C. G.; Warren, T. H.;* Kehr, G.; Erker, G.* 
Isr. J. Chem. 201555, 210-215.

2014

(57)  Copper(II) Anilides in sp3 C-H Amination. Jang, E. S.; McMullin, C. L.; Käß, M.; Meyer, K.*; Cundari, T. R.*; Warren, T. H.*
J. Am. Chem. Soc. 2014136, 10930–10940.

(56)  Frustrated Lewis Pair Modification by 1,1-Carboboration: Disclosure of a Phosphine Oxide Triggered Nitrogen Monoxide Addition to an Intramolecular P/B Frustrated Lewis Pair.
Liedtke, R.; Scheidt, F.; Ren, J.; Schirmer, B.; Cardenas, A. J.; Daniliuc, C. G.; Eckert, H.; Warren, T. H.; Grimme, S.; Kehr, G.; Erker, G.*
 J. Am. Chem. Soc. 2014136, 9014–9027.

(55)  Conversion of Nitrite to Nitric Oxide at Zinc via S-Nitrosothiols 
Cardenas, A. J.; Abelman, R.; Warren, T. H.
Chem. Commun. 201450, 168–170.

2013

(54)  Copper(I) Nitrosyls from Reaction of copper(II) Thiolates with S-Nitrosothiols: Mechanism of NO Release from RSNOs at Cu. Zhang, S.; Çelebi-Ölçüm, N.*; Melzer, M. M.; Houk, K. N.; Warren, T. H.* 
J. Am. Chem. Soc. 2013135, 16746–16749.

(53)  Copper C-nitroso Compounds: Activation of Hydroxylamines and NO Reactivity.
Williams
, K. D.; Cardenas, A. J. P.; Oliva, J. D.; Warren, T. H.* 
Eur. J. Inorg. Chem2013, 3812-3816.

 

(52)  Mechanistic Insights into C-H Amination via Dicopper Nitrenes.
Aguila, M. J.; Badiei, Y. M.; Warren, T. H.*

J. Am. Chem. Soc. 2013135, 9399–9406.

(51)  Noninteracting, Vicinal Frustrated P/B-Lewis Pair at the Norbornane Framework: Synthesis, Characterization, and Reactions. Sajid, M.; Kehr, G.; Wiegand, T.; Eckert, H.; Schwickert, C.; Pöttgen, R.; Cardenas, A. J.; Warren, T. H.; Fröhlich, R.; Daniliuc, C. G.; Erker, G. 
J. Am. Chem. Soc. 2013135, 8882–8895.

(50)  β-Diketiminato Nickel Imides in Catalytic Nitrene Transfer to Isocyanides. 
Wiese, S.; Aguila, M. J. B.; Kogut, E.; Warren, T. H.*
Organometallics201332, 2300-2308.

(49)  Radical Frustrated Lewis Pairs. Warren, T. H.; Erker, G. Top. Curr. Chem. 2013334, 219–238.

(48)  Three coordinate models for the binuclear CuA electron- transfer site. Zhang, S.; Warren, T. H. Chem Sci. 20134, 1786-1792.

2012

(47)  Copper-Catalyzed sp3 C–H Amination. Gephart, R.; Warren, T. Organometallics 201231, 7728-7752.

(46)  Reaction of Cu(I) with Dialkyl Peroxides: Cu(II)-Alkoxides, Alkoxy Radicals, and Catalytic C-H Etherification. Gephart, R. T.; McMullin, C. L.; Sapiezynski, N. G.; Jang, E. S.; Aguila, M. J.; Cundari, T. R.; Warren, T. H. J. Am. Chem. Soc. 2012134, 17350–17353.

(45)  A copper(II) Thiolate from Reductive Cleavage of an S-Nitrosothiol. Melzer, M. M.; Mossin, S.; Cardenas, A. J.; Williams, K. D.; Zhang, S.; Meyer, K.; Warren, T. H. Inorg. Chem. 2012, 51, 8658–8660.

(44)  C-H Functionalization Reactivity of a Nickel-Imide. Wiese, S.; McAfee, J. L.; Pahls, D. R.; McMullin, C. L.; Cundari, T. R.; Warren, T. H. J. Am. Chem. Soc. 2012134, 10114–10121.

(43)  Catalytic C-H Amination with Aromatic Amines. Gephart, R. T.; Huang, D. L.; Aguila, M. J.; Schmidt, G.; Shahu, A.; Warren, T. H. Angew. Chem. Int. Ed. 201251, 6488–6492.

 

(42)  N,N-Addition of Frustrated Lewis Pairs to Nitric Oxide: An Easy Entry to a Unique Family of Aminoxyl Radicals. Sajid, M.; Stute, A.; Cardenas, A. J.; Culotta, B. J.; Hepperle, J. A.; Warren, T. H.; Schirmer, B.; Grimme, S.; Studer, A.; Daniliuc, C. G.; Fröhlich, R.; Petersen, J. L.; Kehr, G.; Erker, G. J. Am. Chem. Soc. 2012134, 10156–10168.

   2011

 

 

 

 

 

 

(41)  Synthesis and Structure-Activity Evaluation of Isatin-β-Thiosemicarbazones with Improved Selective Activity toward Multidrug-Resistant Cells Expressing P-Glycoprotein. Hall, M. D.; Brimacombe, K. R.; Varonka, M. S.; Pluchino, K. M.; Monda, J. K.; Li, J.; Walsh, M. J.; Boxer, M. B.; Warren, T. H.; Fales, H. M.; Gottesman, M. M. J. Med. Chem. 201154, 5878–5889.

 

 

 

 

 

 

 


(40) Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent N-Oxyl Radical. Cardenas, A. J.; Culotta, B. J.; Warren, T. H.; Grimme, S.; Stute, A.; Fröhlich, R.; Kehr, G.; Erker, G. Angew. Chem. Int. Ed. 201150, 7567–7571.

   2010

(39)  Catalytic C-H Amination with Unactivated Amines through copper(II) Amides. Wiese, S.; Badiei, Y. M.; Gephart, R. T.; Mossin, S.; Varonka, M. S.; Melzer, M. M.; Meyer, K.; Cundari, T. R.; Warren, T. H. Angew.Chem. Int. Ed. 201049, 8850–8855.

(38)  Copper 2,4-bis-(2,6-diisopropylphenylimido)pentyl chloride (LMe,iPr2CuCl). Holland, P. L.*; Melzer, M. M.; Warren, T. H.* Inorg. Synth. 201035, 54-55.

(37)  Bis[copper 2,4-bis-(2,4,6-trimethylphenylimido)pentyl]toluene, (LMe,Me3Cu)2(μ-η2:η2-C7H8). Badiei, Y. M.; Warren, T. H.*; Chiang, K. P.; Holland, P. L. " Inorg. Synth. 201035, 50-53.

(36)  Nickel 2,4-bis-(2,6-diisopropylphenylimido)pentyl chloride dimer, [LMe,iPr2Ni(μ-Cl)]2. Dugan, T. R.; Holland, P. L.*; Wiese, S.; Warren, T. H.* Inorg. Synth. 201035, 48-50.

(35)  β-Diketiminate Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3(LMe,Me3= 2,4-bis(mesitylimido)pentyl). Melzer, M. M.; Kogut, E.; Varonka, M. S.; Wiese, S.; Warren, T. H.*; Rocks, S. S.; Holland, P. L. Inorg. Synth. 201035, 45-48.

(34)  β-Diketiminate Supported Manganese and Zinc Complexes. Roesky, H. W.;* Varonka, M. S.; Warren, T. H.* Inorg. Synth201035, 34-38.

(33)  β-Diketiminate Supported Vanadium and Chromium Chloride Complexes. Puttnual, C.; MacAdams, L. A.; Theopold, K. H.*; Badiei, Y. M.; Warren, T. H.* Inorg. Synth. 201035, 30-35.

(32)  β-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3 (LMe,Me3 = 2,4-Bis- (2,6-mesitylimido)pentyl). Varonka, M. S.; Warren, T.H.*; Dugan, T. R.; Cowley, R. E.; Holland, P. L. Inorg. Synth. 201035, 4-8.

(31)  Complexes of Bulky β-Diketiminate Ligands. Introduction. Mindiola, D. J.*; Holland, P. L.*; Warren, T. H.* Inorg. Synth. 201035, 1-4.

(30)  Three-Coordinate copper(II) Amide from Reductive Cleavage of a Nitrosamine. Melzer, M. M.; Mossin, S.; Dai, X.; Bartell, A. M.; Kapoor, P.; Meyer, K.; Warren, T. H. Angew. Chem. Int. Ed. 201049, 904–907.

(29)  Three Coordinate N-heterocyclic Carbene Nickel Nitrosyl Complexes. Varonka, M. S.; Warren, T. H.* Organometallics 201029, 717-720.

   2009

(28)  Nitric Oxide Oxidatively Nitrosylates Ni(I) and Cu(I) C-Organonitroso Adducts. Wiese, S.; Kapoor, P.; Williams, K. D.; Warren, T. H. J. Am. Chem. Soc. 2009131, 18105–18111.

(27)  Reversible RS-NO Bond Cleavage and Formation at copper(I) Thiolates. Melzer, M. M.; Li, E.; Warren, T. H. Chem. Commun. 2009, 5847–5849.

(26)  S-Nitrosothiol and Nitric Oxide Reactivity at Zinc Thiolates. Varonka, M. S.; Warren, T. H. Inorg. Chem. 200948, 5605–5607.

   2008

(25)  Copper-Nitrene Complexes in Catalytic C-H Amination. Badiei, Y. M.; Dinescu, A.; Dai, X.; Palomino, R. M.; Heinemann, F. W.; Cundari, T. R.; Warren, T. H. Angew. Chem. Int. Ed. 200847, 9961–9964.

(24)  Reductive Cleavage of O-, S-, and N-Organonitroso Compounds by nickel(I) β-Diketiminates. Melzer, M. M.; Jarchow-Choy, S.; Kogut, E.; Warren, T. H. Inorg. Chem. 200847, 10187–10189.

   2007

(23)  Preface - Insertion chemistry of the metal-carbon bond: A tribute to Gerhard Erker. Warren, T. H.* J. Organometal. Chem. 2007692, xvii-xix.

(22)  Solid-State (63)Cu and (65)Cu NMR Spectroscopy of Inorganic and Organometallic copper(I) Complexes. Tang, J. A.; Ellis, B. D.; Warren, T. H.; Hanna, J. V.; Macdonald, C. L.; Schurko, R. W. J. Am. Chem. Soc. 2007129, 13049–13065.

(21)  S-Nitrosothiol and Nitric Oxide Reactivity at β-Diketiminato Zinc-Thiolates. Varonka, M. S.; Warren, T. H.* Inorg. Chim. Acta 2007360, 317-328. Special invited contribution to their Top 40 Under 40 issue – The Next Generation

 

 

 

   2006

(20)  Transient Terminal Cu-Nitrene Intermediates from Discrete Dicopper Nitrenes. Badiei, Y. M.; Krishnaswamy, A.; Melzer, M. M.; Warren, T. H. J. Am. Chem. Soc. 2006128, 15056–15057.

   2005

(19)  A Terminal Ni(III)-Imide with Diverse Reactivity Pathways. Kogut, E.; Wiencko, H. L.; Zhang, L.; Cordeau, D. E.; Warren, T. H. J. Am. Chem. Soc. 2005127, 11248–11249.

(18)  Electronic structure and electrophilic reactivity of discrete copper diphenylcarbenes. Badiei, Y. M.; Warren, T. H. Journal of Organometallic Chemistry 2005690, 5989–6000.

   2004

(17)  Non-linear optically active zinc and cadmium p-pyridinecarboxylate coordination networks. Ayyappan, P.; Sirokman, G.; Evans, O. R.; Warren, T. H. and Lin, W.* Inorg. Chim. Acta 200437, 3999-4004.

(16)  Cu(I) β-Diketiminates for Alkene Aziridination: Reversible Cu-Arene Binding and Catalytic Nitrene Transfer from PhI=NTs. Amisial, L. D.; Dai, X.; Kinney, R. A.; Krishnaswamy, A.; Warren, T. H. Inorg. Chem. 200443, 6537–6539.

(15)  Structure and Dynamics of Neutral β-H Agostic Nickel Alkyls: A Combined Experimental and Theoretical Study. Kogut, E.; Zeller, A.; Warren, T. H.; Strassner, T. J. Am. Chem. Soc. 2004126, 11984–11994.

(14)  Discrete Bridging and Terminal Copper Carbenes in Copper-Catalyzed Cyclopropanation. Dai, X.; Warren, T. H. J. Am. Chem. Soc. 2004126, 10085–10094.

(13)  [Me2NN]Co(η6-Toluene): O=O, N=N, and O=N Bond Cleavage Provides β-Diketiminato Cobalt μ-Oxo and Imido Complexes. Dai, X.; Kapoor, P.; Warren, T. H. J. Am. Chem. Soc. 2004126, 4798–4799.

   2003

(12)  Three-coordinate β-diketiminato nickel nitrosyl complexes from nickel (I)-lutidine and nickel (II)-alkyl precursors. Puiu, S. C.; Warren, T. H. Organometallics 200322, 3974-3976.

(11)  Neutral β-diketiminato nickel (II) monoalkyl complexes. Wiencko, H. L.; Kogut, E.; Warren, T. H. Inorg. Chim. Acta 2003345, 199-208.

   2001

(10)  New Open Frameworks Based on Metal Pyridylphosphonates. Ayyappan, P.; Evans, O. R.; Foxman, B. M.; Wheeler, K. A.; Warren, T. H.; Lin, W. Inorg. Chem. 200140, 5954-5961.

(9)   Dioxygen Activation by a β-Diketiminato Cu(I) Ethylene Complex. Dai, X.; Warren, T.H.* Chem. Commun. 2001,

 

 

 

   1993-2000

Publications from Postdoctoral, Graduate, and Undergraduate Studies

(8)   Formation and Structural Properties of Salicylaldiminato Complexes of Zirconium and Titanium. Strauch, J; Warren, TH; Erker, G; Fröhlich, R.; Saarenketo, P. Inorg. Chim. Acta. 2000, 810-821.

(7)   1, 3-Doubly Bridged Group 4 Metallocenes by Intramolecular Reductive Coupling of Pendant Olefins. Warren, T. H.; Erker, G.; Fröhlich, R.; Wibbeling, B. Organometallics 200019, 127-134.

(6)   a-Hydrogen Migration Reactions in Tungsten(VI) Cyclopentadienyl Alkylidyne Complexes. Warren, T. H.; Schrock, R. R.*; Davis, W. M. J. Organomet. Chem.1998569, 125-137.

(5)   Neutral and Cationic Group 4 Complexes Containing Bis (borylamide) Ligands,[R2BNCH2CH2NBR2]2-(R= 2, 4, 6-I-Pr3C6H2, M= Zr; R= Cyclohexyl, M= Ti, Zr, Hf). Warren, T. H.; Schrock, R. R.; Davis, W. M. Organometallics 199817, 308-321.

(4)   Synthesis of Group 4 Organometallic Complexes That Contain the Bis (borylamide) Ligand [Mes2BNCH2CH2NBMes2]-2. Warren, T. H.; Schrock, R. R.; Davis, W. M. Organometallics 199615, 562-569.

(3)   Iron(0) Arene and Iron(II) Hydride Complexes from the Hydrogenation or Thermolysis of High-spin Iron(II) Alkyls. Hermes, A. R.; Warren, T. H.‡; Girolami, G. S.* J. Chem. Soc., Dalton Trans.1995, 301-305.

(2)   Ligand Electronic Effects in Asymmetric Catalysis: Enhanced Enantioselectivity in the Asymmetric Hydrocyanation of Vinylarenes. Casalnuovo, A. L.; Rajan Babu, T. V.; Ayers, T. A.; Warren, T. H. J. Am. Chem. Soc. 1994, 116, 9869–9882.

(1)   Surface-Selective Deposition of Palladium and Silver Films from Metal-Organic Precursors: A Novel Metal-Organic Chemical Vapor Deposition Redox Transmetalation Process. Lin, W.; Warren, T. H.; Nuzzo, R. G.; Girolami, G. S. J. Am. Chem. Soc.1993115, 11644-11645.

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